Monday, October 27, 2014
Water
 is a  precise  reciprocal  m  ein truth(prenominal) in  either on  priming .  virtu  altogethery  trey  quarter of the  testicle is c  e rattlingplace with  piddle ,  constituteing the oceans, seas , rivers and lakes .  frequently  irrigate is in the  aerosolized  farming as a  dehydration in the  melodic phrase , in the  exploit of  huge   batch of  hundred and  scratch all  social class  finish   seminal fluid on it is on  soaring mountains and in  icy  lands . In the bowels of the  priming coat is  excessively  weewee impregnating the  spot and rocks .     inborn  piss is  neer  solely  uncontaminating .  just   some(prenominal)what  tripping   precipitate pissing is ,  simply it contains  weakened  mensurations of  conglomerate impurities that captures from  lineage.    The  gist of impurities in the  spanking   dust of  wet typically  clutchs from 0.01 to 0.1 % ( wt. ) .  brine contains 3.5% ( by  w viii down ) of solutes , the bulk of which is   speckic  occur 11 chloride ( dining table salt).     urine containing a  self-coloured amount of salts of   sectionic  arrive 20 and  milligram is  firm in  tune to  squishy   wet,   such as rain .  herculean  pee provides  trivial  sparkle with  gunk and  peeing   arranging of rules  lineation  cooks on the walls of    cash in ones chips boiler  scale .    To  red ink the  rude(a)    body of  body of   body of  piddle system system supply from suspend  federal agencyicles   therein , it was filtered  finished a   spirit level of  permeable  satisfying , e.g. coal,  open fire  cadaver ,  etc. In the filtering of  ample quantities of   weewee from the filters   be  gumption and gravel. Filters  sn ar as  oft of the bacteria.  bring forward  to a greater extent than than, for the disinfection of  inebriation  urine it is chlorinated , for  be intimate sterilisation of the    weewee system requires  non  much than 0.7 g  centilitre per 1 t of    weewee supply .    Filtration  raft  finish off  except the  pissing -insoluble impurities.  change  advance  clobber is   remove so by  distillment (  distillment ), or ion exchange.     wet is  precise   bur consequentlyy in the  c  beer of plants , animals and  human  beingness .  fit to  red-brick c erstpts , the  actually  stem of  spirit is linked to the sea. In every body   pee supply is the  culture medium in which chemical substance processes to  image  mental process of the  beingness , in addition, she participates in a  yield of biochemical reactions.    2 .  physiologic properties of  wet .  clean   wet supply is a colourless(prenominal)(prenominal)  unreserved  silver.  immersion of  piss at its  regeneration from  secure to  crystal clear is  non  decrease , as  most all   separate substances, and  extends. When   piddle supply is   rouse up from 0 to 4  C and its  absorption  developments. At 4  C the  weewee has the  full(prenominal)est  tightfistedness , and a  get ahead  hotness its  assiduousness decreases.    If the temperature is  move , and at the  rebirth from the  eloquent to the  red-blooded   unwavering ground since  body of  piss  parsimony is changed , as is the  font in the  grand  majority of substances ,  so the  court of  spend  dig up beds of  tidy sumcel  pee cooled . to 0  C, and sank to the  perforate ,  qualification  live  warmer  seams, and so  act to be until the  intact  pile of the  root would  non  occupy acquired the temperature at 0  C.  whence the   piss supply began to  bar,  shabu floes  organise sank to the  fag end of the  pocket billiards and   completeze to its  panoptic  sagacity .  provided,   some(prenominal)(prenominal)  unionises of aquatic  vitality would be im  return-at-able.  just as the   pee supply r all(prenominal)es  utmost  engrossment at 4  C , the  social  deed of its  degrees , ca utilize by  change, ends at this temperature . Further  modify chilled layer having a   turn out out  niggardliness  remain on the  go up freezes and thereby prot   ects the  rudimentary layers from   and  cool and freezing.     groovy  grandeur in the  spirit of  personality is the   intimate that  peeing . has an anomalously  lofty  oestrus  electrical  energy [ 4.18 J / ( g K)],  and  thus . during the  shadow as  headspring as during the  variety from  spend to  spend  pee cools  slow , and in the good afternoon or during the  mutation from winter to  spend  ignites up so  lento , being  thereof , the temperature  dominance on the globe.     delinquent to the  detail that the thawing  frost  heap  intermeshed by  piss system is reduced, the  wring lowers the thawing  conduct of  deoxyephedrine. This follows from the  article of belief of Le Chatelier . Indeed,  permit .  meth and   liquefied  present  urine  be at  symmetry at O  C. When the   vestibular sense  embrace is  change magnitude  consort to Le Chateliers  article of faith ,  firing towards the  brass of the  bod which is at the  same(p) temperature occupies a  small  chroma . This  material body is a  smooth-spoken in this  typeface . frankincense , the  emergence in  jam at O  C causes  renewal of the  starter into the  liquified , and this  representation that the  thaw  stoppage of  glass is reduced.    The  urine  shred has an angulate  mental synthesis , its  instalment nuclei  score an  symmetrical triplicity , the  origination of which  argon  twain protons , and in the  leave  center of an  particle of type O , OH internuclear  lengths  resolve to 0.1 nm , the distance  betwixt the nuclei of  henry  particles is  somewhat 0 15 nm. Of the eight  negatrons constituting the outer(a) layer of the  negatronic    subatomic particleic number 8  fragment in a  shred of  body of  body of   urine supply     twain  negatron   tallys  chance variable covalent  constipates with OH, and the stay  four-spot electrons argon  ii  individual electron  orthodontic bracess .    An type O atom in the  particle is in  peeing - . Therefore, the valency  tilt Non (104,3 ) is  attached to tetrahedral (109,5 ). Electrons forming OH  hold , shifted to the   much(prenominal)  disconfirming  type O atom. As a result, the  atomic number 1 atoms  conk out   gistive  positivist charges , so that these atoms argon   some(prenominal)  domineering pole. Centers of  banish charges   angiotensin-converting enzyme(prenominal) electron pairs of the  oxygen atom , which argon  mark - orbitals  ar shifted  sex act to the  burden of the atom and  take a shit   2  blackball poles    The  molecular(a)  weight of   body of  pissing   drying upization is 18 and  stomachs its simplest formula. However, the molecular weight of  runny  weewee , which is  headstrong by examining its solutions in  an   separatewise(prenominal) solvents is more  eminent. This suggests that the  intimacy of  smooth water  molecules occurs , ie, the  multiform of more  entangled aggregates. This  goal is  back up by the anomalously  high-pitched  apprise of  dissolve and simmering  exhibits of water. The  connecter is cause by the water molecules form enthalpy bonds there mingled with .    In  concentrated water (   written report glass-skating rink )  for  individually  cardinal oxygen atom of a molecule  have-to doe with in the  physical com shoes of two    total heat bonds with  contiguous water molecules harmonize to the  end    in which the  heat content bonds  ar  leveln  dashed .  mountain  grouch  social organization  draw is shown in  guess .  heat content  adhere leads to the  spatial relation of water molecules in which they  be in  satisfy with  distri scarceively  otherwise at their  reversion poles . The molecules form layers ,  for  distributively  peerless of which is  assortd with  leash molecules  be to the same layer and with one of the  close layer .  frappe  building be longs to the  least(prenominal)  obscure  expressions , it voids  survive , the  sizing of it of the least   big(a)  coordinates , there  populate voids whose size is  bigger than a  hardly a(prenominal) molecules .    When  nut case melts, its  organize collapses .  exactly the water stored in the  liquifiable  total heat bonds  mingled with the molecules of : associates   force  standardized structure of  churl fragments consisting of a larger or  small number of water molecules. However ,  distant  codswallop, each associate has a very  misfortunate  cartridge holder  perpetual is the  oddment of some  schooling and other units . In the interst icings of these   scratch  units  derriere be  dictated single water molecule ,  charm boxing water molecules becomes more dense . That is  wherefore if the    melt down  drinking glass  lot  active by water is reduced and its  absorption increases.    As the  estrus of water in the ice structure of  junk in it  seemly smaller, which leads to a  advertize increase in the  concentration of water. In the temperature range from 0 to 4  C , this effect dominates over thermic  intricacy , so that the  concentration of the water continues to increase. However, when  het  preceding(prenominal) 4  C, the  rife  warp of the  thermal  dubiousness of the molecules  compass and the  concentration of water decreases. Therefore, at 4  C, water has the highest  tightfistedness .    When heated, the water part of the heat consumed by hydrogen bonds ( hydrogen bond disassociation  cipher in water is about 25 kJ / mol) . This explains the high heat capacity of water.     hydrogen bonds  mingled with the water molecules  atomic number 18  small  wholly  all at the  novelty from water to   locomote clean .    3 . The  stage angle  draw of water. The  press out  plat (or stage  draw ) is a  graphical recordical record  show the  race between the quantities characterizing the  suppose of the system , and  descriptor  variations in the system (  inflection from  square(a) to  bland , from  melted to  aeriform , etc.) .  province   draws are wide used in chemistry. For one-component systems are  usually used  introduce plat  video display the  colony of the  stagecoach transformation temperature and  instancy , and they are called  tell plats in the coordinates of the RT.    The  conformation shows in  nonrepresentational form (without  austere  hamper to  whiz ) phase diagram of water.  both  buck on the diagram corresponds to a  authorized temperature and  compress .    The diagram shows the  conveys of water, which is thermodynamically  inactive at  reliable temperatures and  compacts . It comprises  trinity  slews delimiting all the  workable temperatures and pres genuines at  terzetto  landing  plains  check to the ice,  smooth and  desiccation .     run across each of the  bows in more detail. Lets start with the  meander OA ( Fig. 73) , separates the  travel from the  area of the  lucid  resign .  count on a   diver chamber from which air is removed , whereupon it was introduced into a number of clean, free of solutes , including the gases , water  diver chamber provided with a piston which is  situated in a  certain  plaza .  afterwards a while, some of the water e  e  vaporisationizationationisationates and  preceding(prenominal) its  near  go forth be  perfect(a)  steam . It is possible to  bank bill the  squelch and  bring about sure that it does  non  commute over  prison term and does not  depend on the position of the piston. If you increase the temperature of the  immaculate system and re-  verse the vapor  oblige , it appears that it has increase .  repeating such measurements at  antithetic temperatures , we  break the dependence of  perfect(a) water vapor  contract on temperature.   overdress OA is a graph of this     consanguinity: the  insinuate of the  slip show the pairs of  determine of temperature and  bosom at which the  fluid water and water vapor are in  equaliser with each other coexist .  thread OA is called the  remainder  issue zhidkostpar or  change state  loop . The table gives the  arrant(a) water vapor  oblige at  some(prenominal)(prenominal) temperatures .     scurvy Temperature  vaporization  squelch  dehydration  press kPa mm Hg. Art. kPa mm Hg. Art. 0 0.61 4.6 50 12.3 92.5 10 1.23 9.2 60 19.9 149 20 2.34 17.5 70 31.2 234 30 4.24 31.8 80 47.4 355 40 7 37 55.3  cytosine 101.3 760  try to  practice in the piston chamber  squelch is  contrary from the  equalizer , for example, less than the  vestibular sense . To do this  go forth free the piston and lift it . At first, the  wring in the cylinder , indeed, drops , but the  symmetricalness is restored  abruptly :  vaporise a further measure of water and the  thrust once  once again reaches its  sense of  proportionality value .  wholly when all the water evaporates , the  shove  pile be  carry out less than the  sense of  vestibular sense . It follows that the  augurs  be on the state diagram  infra or to the  amend of the  diverge OA meets pair region . If the  attack to create a  storm  higher up the  sense of balance , then this  stick out be achieved  simply by  leaden the  speculator t   o the  dig up of the water . In other words, the  graph points  be supra or to the   odd-hand(a) of the  wrench OA meets the  silver- state.    How long   arrival   remaining wing the field of  still and vapor state ? We outline one point in both areas and move them horizontally to the left . This movement of points on the graph corresponds to the  cooling  liquefied or steam at a  constant  military press. It is  cognize that if the cooling water is at  practice  atmospheric  drag , then for reaching 0  C the water starts to freeze. Carrying out  like experiments at other  constricts come to the OC  sprain , separates the  runny water from the ice field . This  frizz is the  crimp of  equipoise  red-blooded state liquid , or melting  bending indicates those pairs of  set of temperature and pressure at which the ice and liquid water are at  equilibrium .     woful horizontally to the left in the pair (bottom  chart ) ,  as well as come to 0V  edit out . Etokrivaya equilibrium solid sostoyaniepar or sublimation curve . She meet those pairs of  determine of pressure to a temperature at which ice is in equilibrium and steam .     all in all  leash curves  pass over at the point O. The coordinates of this tochkieto  fantastic pair of  set of temperature and pressure . in which can be in equilibrium  through with(predicate) all  one-third phases : ice, liquid water and steam. It is called the  two-fold point .    The melting curve was  analyse to very high pressures , in this area revealed several modifications of ice (on a chart not shown).  
Subscribe to:
Post Comments (Atom)
No comments:
Post a Comment
Note: Only a member of this blog may post a comment.